{2-[(4-Bromophenyl)iminomethyl]pyridine-κ2 N,N′}diiodidozinc(II)
نویسندگان
چکیده
In the title compound, [ZnI(2)(C(12)H(9)BrN(2))], the metal centre displays a moderately distorted tetra-hedral coordination geometry defined by two iodide anions and two N atoms of the organic ligand. The dihedral angle between the pyridine and benzene rings is 15.15 (13)°.
منابع مشابه
Dibromido{2-[(4-bromophenyl)iminomethyl]pyridine-κ2 N,N′}zinc(II)
In the title complex, [ZnBr(2)(C(12)H(9)BrN(2))], the Zn(II) ion is in a distorted tetra-hedral coordination environment formed by two imine N atoms of the bis-chelating N-heterocyclic ligand and two Br atoms. The dihedral angle between the pyridine and benzene rings is 8.04 (17)°.
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The unique Hg(II) ion in the title centrosymmetric dinuclear complex, [Hg(2)Cl(4)(C(12)H(9)BrN(2))(2)], is in a distorted trigonal-bipyramidal coordination environment formed by the bis-chelating N-heterocyclic ligand, two bridging Cl atoms and one terminal Cl atom. One of the bridging Hg-Cl bonds is significantly longer than the other.
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In the crystal structure of the title compound, [Cu(C(12)H(9)BrN(2))(2)](C(24)H(20)B), the copper(I) cation is coordinated by four N atoms of two crystallographically independent 2-[(4-bromo-phen-yl)imino-meth-yl]pyridine ligands within a distorted tetra-hedron.
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In the title complex, [ZnBr(2)(C(12)H(9)FN(2))], the Zn(II) atom has a distorted tetra-hedral Br(2)N(2) coordination sphere. The organic ligand is bidentate, coordinating the Zn(II) atom via two imine N atoms. The benzene and pyridine rings are oriented at a dihedral angle of 10.49 (1)°. In the crystal, weak C-H⋯F and C-H⋯Br hydrogen bonds are observed.
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